Yes you can use shout on shoes to clean them.
Just take some shout and spray the stain or shoes with the shout and let the shout sit on the shoes for a few minutes or so.
Then take a toothbrush and scrub the stain out of the shoe.
After you scrub the stain with the toothbrush take a wet washcloth and wipe down the shoes to remove the stain and shout.
You can also use baking soda and vinegar to clean your shoes and remove stains as well but shout also works great.
Then you can soak your shoes in some water with some baking soda or laundry detergent and wash your shoes by hand.
Or you can place the shoes into a washing machine to wash them.